| 一种镧系-过渡金属二维氰桥配合物[Nd(DMSO)2(H2O)2][Ni(CN)4]Cl(DMSO=二甲亚砜)的合成和晶体结构(英) |
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| 引用本文： | 梁淑惠,车云霞,郑吉民. 一种镧系-过渡金属二维氰桥配合物[Nd(DMSO)2(H2O)2][Ni(CN)4]Cl(DMSO=二甲亚砜)的合成和晶体结构(英)[J]. 无机化学学报, 2005, 21(7): 1055-1059 |
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| 作者姓名： | 梁淑惠 车云霞 郑吉民 |
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| 作者单位： | 南开大学化学学院,天津,300071 |
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| 基金项目： | 国家自然科学基金资助项目(No.50242001)。 |
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| 摘 要： | The cyano-bridged bimetallic complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl with two-dimensional gridding molecule structure was synthesized and characterized. In the complex all four cyano groups of unit Ni(CN)42- are bound to Nd3+ ions. The crystal data for the title complex: monoclinic, space group P21/c, a=0.780 0(3) nm, b=1.509 7(6) nm, c=1.683 2(6) nm, β=115.231(14)°, Z=4, μ=4.311 mm-1, final R1=0.020 9, wR2=0.045 4. CCDC: 272214.
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| 关 键 词： | 氰桥配合物； 镧系-过渡金属配合物； 二甲亚砜 |
| 文章编号： | 1001-4861(2005)07-1055-05 |
| 收稿时间： | 2004-07-12 |
| 修稿时间： | 2004-07-12 |
Synthesis and Crystal Structure of a Cyano-Bridged Lanthanide-Transition-Metal Complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl (DMSO=Dimethylsulfoxide) with Two-dimensional Gridding Molecule Structure |
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| LIANG Shu-Hui,CHE Yun-Xia and ZHENG Ji-Min. Synthesis and Crystal Structure of a Cyano-Bridged Lanthanide-Transition-Metal Complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl (DMSO=Dimethylsulfoxide) with Two-dimensional Gridding Molecule Structure[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(7): 1055-1059 |
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| Authors: | LIANG Shu-Hui CHE Yun-Xia ZHENG Ji-Min |
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| Affiliation: | Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071 and Department of Chemistry, Nankai University, Tianjin 300071 |
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| Abstract: | The cyano-bridged bimetallic complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl with two-dimensional gridding molecule structure was synthesized and characterized. In the complex all four cyano groups of unit Ni(CN)42- are bound to Nd3+ ions. The crystal data for the title complex: monoclinic, space group P21/c, a=0.780 0(3) nm,b=1.5097(6) nm, c=1.683 2(6) nm, β=115.231(14)°, Z=4, μ=4.311 mm-1, final R1=0.020 9, wR2=0.045 4. CCDC:272214. |
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| Keywords: | cyano-bridged complex lanthanide-transition metal complex DMSO |
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