Mild mono and double demethylation in dimethylsulfonium substituted ruthenacarborane complexes. A regioselective reaction |
| |
| Authors: | Planas Jose Giner Vinas Clara Teixidor Francesc Hursthouse Michael B Light Mark E |
| |
| Institution: | Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B, 08193 Bellaterra, Spain. |
| |
| Abstract: | Reaction of RuCl(2)(eta(6)-C(6)H(6))](2) with 10-(CH(3))(2)S-7,8-nido-C(2)B(9)H(10)](-) or 9-(CH(3))(2)S-7,8-nido-C(2)B(9)H(10)](-) afforded the expected cationic complexes Ru(eta(5)-n-(CH(3))(2)S-7,8-C(2)B(9)H(10))(eta(6)-C(6)H(6))](+)(n= 10, (1); 9, (3)), but also the unexpected neutral Ru(eta(5)-10-HS-7,8-C(2)B(9)H(10))(eta(6)-C(6)H(6))(2) or Ru(eta(5)-9-(CH(3))S-7,8-C(2)B(9)H(10))(eta(6)-C(6)H(6))(4) by double and mono demethylation of the (CH(3))(2)S moiety, respectively. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
