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Electrochemical deposition of electrochromic niobium oxide films from an acidic solution of niobium peroxo complexes
Authors:S S Fomanyuk  Yu S Krasnov  G Ya Kolbasov  V N Zaichenko
Institution:1588. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
Abstract:Deposition of electrochromic niobium(V) oxide films from an acidic solution of niobium peroxo complexes on a transparent conducting cathode in the form of an SnO2 film on glass was studied. With an increase in the negative potential of the deposition of niobium(V) oxide films from a solution of niobium peroxo complexes at pH 2.5, the structure and composition of the films changed. A study of the electrochromic properties of Nb2O5 films revealed broadening of the bands in the electrochromic coloration spectrum with an increase in the negative potential of the deposition.
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