Uranium pyrrolylamine complexes featuring a trigonal binding pocket and interligand noncovalent interactions |
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| Authors: | Lewis Andrew J Williams Ursula J Kikkawa James M Carroll Patrick J Schelter Eric J |
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| Affiliation: | P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA. |
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| Abstract: | The syntheses of tri- and tetravalent uranium complexes of the Ar(F)(3)TPA(3-) ligand [Ar(F) = 3,5-bis(trifluoromethyl)phenyl; TPA = tris(pyrrolyl-α-methylamine)] are described. Interligand noncovalent interactions between arene groups within the complexes are detected both in the solid state and in solution. |
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