Mono- and binuclear Schiff base complexes derived from glycine, 3-acetylpyridine and transition metal ions |
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Authors: | Nawar Nagwa A. Shallaby Abdel-Hamid M. Hosny Nasser M. Mostafa Mohsen M. |
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Affiliation: | (1) Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt |
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Abstract: | Binuclear Schiff base complexes derived from glycine (Gly) and 3-acetylpyridine (3-APy) in the presence of M(OAc)2 [M = CoII, NiII, CuII, ZnII and CdII] have been synthesized. The role of pH in promoting the condensation of glycine and 3-acetylpyridine, as well as the substitution of acetates by hydroxide ion, has been discussed. Also, the reaction of glycine with 3-acetylpyridine in the presence of MCl2 [M = CoII and NiII] and MCl3 [M = FeIII and CrIII] yields mono- and/or binuclear complexes containing both of glycine and 3-acetylpyridine without condensation. Both types of complex were isolated and characterized by chemical analysis, conductance, spectral (u.v.–vis., i.r., and 1H-n.m.r.), magnetic and thermal measurements. |
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