Synthesis and Crystal Structures of S
2
O
2
Macrocycle L, and its Silver(I) and Platinum(II) Complexes (Where L = 5,8-dioxa-2,11-dithia-[12]-o-cyclophane) |
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Authors: | Il Yoon Ki-Min Park Jong Hwa Jung Jineun Kim Sung Bae Park Shim Sung Lee |
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Institution: | (1) Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Chinju, 660-701, S. Korea |
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Abstract: | The S2O2-donor macrocycle, L(5,8-dioxa-2,11-dithia-12]-o-cyclophane or 3,4-benzo-1,6-dithia-9,12-dioxocyclo-tetradecane-3-ene) was synthesized by ring closure reaction of 2,2'-(ethylenedioxy)diethanethiol with , '-dibromo-o-xyleneunder high dilution and crystallized from methanol. The X-ray structure of L has a C2 axis and is shown to have two S atoms oriented exodentate and two O atoms positionedendodentate to the ring cavity. Reaction of AgNO3 with L affords monomeric Ag(L)(NO3)], (1)in which the Ag atom is in a distorted trigonal plane coordinated by two S atoms in a ring and to one O atom from the NO3
- ion. The behavior of complex 1 in solution was also characterized by NMR titration. Reaction between K2PtCl4 and L affords Pt(L)Cl2], (2) in which the Pt atom has a distorted square-planar environment, coordinated to two S atoms of Land to two Cl- ions in a cis arrangement. |
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Keywords: | thiaoxa macrocycles synthesis crystal structures silver(I) complex platinum(II) complex NMR titration |
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