Asymmetric silyl nitronate cycloadditions with bornane-10,2-sultam derivatives |
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| Authors: | Byeang Hyean Kim Ju Young Lee |
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| Institution: | Department of Chemistry, Center for Biofunctional Molecules, Pohang Institute of Science and Technology, P. O. Box 125, Pohang 790-600, Korea |
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| Abstract: | Asymmetric silyl nitronate cycloadditions with N-acryloyl (2R)-bornane-10,2-sultam, N-acryloyl (2S)-bornane-10,2-sultam, and N-methacryloyl (2R)-bornane-10,2-sultam have been studied. The asymmetric silyl nitronate cycloaddidon/elimination methodology provides a general route for the asymmetric synthesis of 2-isoxazolines. |
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