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Synthesis of Mesoporous Cu-Mn-Al_2O_3 Materials and Their Applications to Preferential Catalytic Oxidation of CO in a Hydrogen-rich Stream
Authors:FANG De-ren  REN Wan-zhong  LIU Zhong-min  XU Xiu-feng  ZHANG Hui-min  LIAO Wei-ping
Institution:[1]Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China [2]Institute of Applied Catalysis, Yantai University, Yantai 264005, P. R. China
Abstract:A series of mesoporous Cu-Mn-Al2O3(CMA) materials was synthesized at moderate temperature and their structures were characterized by XRD, N2 physical adsorption and TPR techniques. It was found that using metal complex ionCu(NH3) 42+-Mn(NH3)62+] as raw materials is easier to form good-structure mesoporous Cu-Mn-Al2O3 materials than using its nitrate salt Cu(NO3)2-Mn(NO3)2]. The TPR tests results indicate that CuO and MnOx were homogeneously dispersed in the mesoporous materials. Their catalytic applicatio...
Keywords:Cu-Mn-Al2O3  Mesoporous material  Selective CO oxidation  Hydrogen-rich  Catalyst  
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