Synthesis and structural reassignment of (+)-epicalyxin F |
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Authors: | Tian Xia Rychnovsky Scott D |
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Institution: | Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California 92697-2025, USA. |
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Abstract: | We have established the structure of (+)-epicalyxin F through chemical synthesis. An acid-promoted rearrangement of synthetic benzopyran 6 led to the identification of the natural product as (3S,5S,7R)-epicalyxin F (22). Comparison with NMR spectra and optical rotation of the natural product confirms our assignment, and the reassigned structure is compatible with the proposed biosynthetic pathway. |
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