Kinetics of Cr(VI) and V(V) oxidation of trans-stilbene and indene |
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| Authors: | P S Radhakrishnamurti H P Panda and D C Pradhan |
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| Institution: | (1) Department of Chemistry, Berhampur University, 760007 Berhampur, India;(2) Department of Chemistry, Rajendra College, Balangir, Orissa, India |
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| Abstract: | Title reactions are acid catalyzed and strongly dependent on the permittivity of the medium. With Cr(VI) indene reacts faster than trans-stilbene, but with V(V), trans-stilbene reacts faster than indene. The mechanism is discussed.
                          .  Cr(VI)  , -, V(V) - , .     ,  .
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