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Di‐μ‐phenyl­thio‐bis­[bis(η5‐methyl­cyclo­penta­dienyl)(tetra­hydro­furan)lanthanum(III)] bis­(tetra­hydro­furan) solvate
Authors:Huanrong Li  Yingming Yao  Qi Shen  Linhong Weng
Abstract:The title complex, La2(C6H7)4(C6H5S)2(C4H8O)2]·2C4H8O, is a centrosymmetric dimer bridged through the S atoms of the benzene­thiolate ligands. The bridging La2S2 unit is completely planar, while the geometry around the nine‐coordinate La atom is that of a distorted trigonal bipyramid. The La—S—La and S—La—S angles are 117.51 (4) and 62.5 (1)°, respectively, and the average La—S bond length is 2.9759 Å. The crystals contain two tetra­hydro­furan solvate mol­ecules for every complex mol­ecule.
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