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On the short carbonyl bond in bis[μ‐1,2‐benzisothiazol‐3(2H)‐one 1,1‐dioxido‐κ2N:O]bis{[1,2‐benzisothiazol‐3(2H)‐one 1,1‐dioxido‐κN]bis(imidazole)copper(II)}
Authors:Pan e Naumov  Gligor Jovanovski  Sheng‐Zhi Hu  Il‐Hwan Suh  Ibrahim Abdul Razak  Suchada Chantrapromma  Hoong‐Kun Fun  Seik Weng Ng
Institution:Panče Naumov,Gligor Jovanovski,Sheng‐Zhi Hu,Il‐Hwan Suh,Ibrahim Abdul Razak,Suchada Chantrapromma,Hoong‐Kun Fun,Seik Weng Ng
Abstract:The short carbonyl bond in the title compound, Cu2(C7H4­NO3S)4(C3H4N2)4] Liu, Huang, Li & Lin (1991). Acta Cryst. C 47 , 41–43], is an artifact of disorder in the iso­thia­zol‐3(2H)‐one 1,1‐dioxide part of the 1,2‐benziso­thia­zol‐3(2H)‐one entity. In the present redetermination, all bond dimensions in the centrosymmetric dinuclear mol­ecule are normal. The five‐coordinate Cu atom shows trigonal–bipyramidal coordination. Hydro­gen bonds from the imidazole donor ligand link adjacent mol­ecules into a two‐dimensional layer structure.
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