Acetonyldichloro[(Z)‐2‐chloro‐2‐phenylvinyl]tellurium(IV), helical chains of metal complexes |
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Authors: | J. Zukerman‐Schpector,Ionel Haiduc,Robinson L. Camillo,Jo o V. Comasseto,Rodrigo L. O. R. Cunha,I. Caracelli |
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Affiliation: | J. Zukerman‐Schpector,Ionel Haiduc,Robinson L. Camillo,João V. Comasseto,Rodrigo L. O. R. Cunha,I. Caracelli |
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Abstract: | The primary geometry about the TeIV atom in the title compound, [TeCl2(C8H6Cl)(C3H5O)] or C11H11Cl3OTe, is a pseudo‐trigonal‐bipyramidal arrangement, with two Cl atoms in apical positions, and the lone pair of electrons and C atoms in the equatorial plane. The TeIV atom is involved in three secondary interactions, two intramolecular [Te?O = 2.842 (3) Å and Te?Cl3 = 3.209 (1) Å] and one intermolecular [Te?Cl = 3.637 (1) Å], the latter giving rise to a helical chain. These helices are linked by C—H?O interchain interactions. |
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