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7‐Chloro‐1‐(2,6‐di­fluoro­phenyl)‐1H,3H‐thia­zolo­[3,4‐a]­benz­imidazole and 1‐(2,6‐di­fluoro­phenyl)‐6‐methyl‐1H,3H‐thia­zolo­[3,4‐a]­benz­imidazole
Authors:Francesco Nicol  Giuseppe Bruno  Rosario Scopelliti  Silvana Grasso  Angela Rao  Maria Zappal
Institution:Francesco Nicoló,Giuseppe Bruno,Rosario Scopelliti,Silvana Grasso,Angela Rao,Maria Zappalá
Abstract:The title mol­ecules, C15H9ClF2N2S and C16H12F2N2S, respectively, display the well known butterfly‐like conformation with a flat thia­zolobenz­imidazole system. In both compounds, the mean plane through the tricyclic system is almost perpendicular to the 2,6‐di­fluoro­phenyl ring. This arrangement of the aryl group is determined by two intramolecular hydrogen bonds and by an attractive F?S interaction.
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