7‐Chloro‐1‐(2,6‐difluorophenyl)‐1H,3H‐thiazolo[3,4‐a]benzimidazole and 1‐(2,6‐difluorophenyl)‐6‐methyl‐1H,3H‐thiazolo[3,4‐a]benzimidazole |
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Authors: | Francesco Nicol Giuseppe Bruno Rosario Scopelliti Silvana Grasso Angela Rao Maria Zappal |
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Institution: | Francesco Nicoló,Giuseppe Bruno,Rosario Scopelliti,Silvana Grasso,Angela Rao,Maria Zappalá |
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Abstract: | The title molecules, C15H9ClF2N2S and C16H12F2N2S, respectively, display the well known butterfly‐like conformation with a flat thiazolobenzimidazole system. In both compounds, the mean plane through the tricyclic system is almost perpendicular to the 2,6‐difluorophenyl ring. This arrangement of the aryl group is determined by two intramolecular hydrogen bonds and by an attractive F?S interaction. |
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