(Z)‐7‐Chloro‐3‐[(3‐chlorophenyl)methylidene]‐4‐p‐tosyl‐3,4‐dihydro‐2H‐1,4‐benzoxazine |
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Authors: | Gopeswar Chaudhuri Madeleine Helliwell Nitya G. Kundu |
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Abstract: | In the title compound, C22H17Cl2NO3S, the molecule is a substituted 3,4‐dihydro‐2H‐1,4‐benzoxazine compound which has three phenyl rings which are essentially planar. The 3,4‐dihydro‐2H‐oxazine part of the molecule is fused to the benzo ring and has a half‐boat conformation; the dihedral angle between the planar part of the oxazine ring and the benzo ring is 10.2 (2)°. The (3‐chlorophenyl)methylidene substituent has a Z configuration in relation to the ring N atom of the oxazine moiety. Interestingly, the p‐toluenesulfonyl (p‐tosyl) substituent on the ring N atom protrudes away from the 3‐chlorophenyl substituent thus avoiding any steric interaction. |
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