首页 | 本学科首页   官方微博 | 高级检索  
     检索      


[N‐(6‐Amino‐3,4‐di­hydro‐3‐methyl‐5‐nitroso‐4‐oxopyrimidin‐2‐yl)glycylglycinato]aquapotassium,a three‐dimensional coordination polymer
Authors:John N Low  Paloma Arranz  Justo Cobo  M Angeles Fontecha  M Luz Godino  Rafael Lpez  Christopher Glidewell
Institution:John N. Low,Paloma Arranz,Justo Cobo,M. Angeles Fontecha,M. Luz Godino,Rafael López,Christopher Glidewell
Abstract:In the title compound, polymeric potassium N‐(6‐amino‐3,4‐di­hydro‐3‐methyl‐5‐nitro­so‐4‐oxopyrimidin‐2‐yl)­glycyl­gly­cinate hydrate, (K+·C9H11N6O5?·H2O)n, the hexacoordinate K+ cation is linked to five different anions as well as to the water mol­ecule, with K—O distances in the range 2.617 (2)–2.850 (2) Å. Four of the O atoms in each anion coordinate to K centres, one of them acting as a bridging ligand, leading to the formation of nearly square centrosymmetric K2O2 rings. The structure is analysed in terms of (010) metal–ligand sheets linked by 010] chains of fused rings.
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号