Ten‐vertex rhodadithiaborane chemistry: [8‐{I(CH2)5}‐3‐(η5‐C5Me5)‐arachno‐3,7,8‐RhS2B8H9] |
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Authors: | Ram n Mací as,Simon A. Barrett,Jonathan Bould,Udo D rfler,Josef Holub,John D. Kennedy,Mark Thornton‐Pett,Bohumil tí br |
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Affiliation: | Ramón Macías,Simon A. Barrett,Jonathan Bould,Udo Dörfler,Josef Holub,John D. Kennedy,Mark Thornton‐Pett,Bohumil Štíbr |
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Abstract: | Neutral 8‐(5‐iodo‐n‐pentyl)‐3‐(η5‐pentamethylcyclopentadienyl)‐arachno‐3‐rhoda‐7,8‐dithiaundecaborane, [Rh(C5H19B8IS2)(C10H15)], obtained from the [arachno‐7,8‐S2B9H10]? anion by treatment with I(CH2)5I followed by [Rh(C5Me5)Cl2]2 and N,N,N′,N′‐tetramethyl‐1,8‐diaminonaphthalene, has the 11‐vertex cluster geometry of [arachno‐7,8‐S2B9H10]?, but with an {Rh(C5Me5)} unit in the 3‐position instead of a {BH} unit, and with a –(CH2)5I chain attached exo to an S atom. |
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