A pseudo‐trigonal bipyramidally coordinated Pt atom in dicarbonylbis(octacarbonyl‐μ‐dicyclohexylphosphidodirhenio)platinum(II) |
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| Authors: | Hans‐Jürgen Haupt Ulrich Flrke Stefanie Klose |
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| Institution: | Hans‐Jürgen Haupt,Ulrich Flörke,Stefanie Klose |
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| Abstract: | In the title compound, PtRe4(C12H22P)2(CO)18] or (μ‐PCy2)(CO)8Re2]2Pt(CO)2 (Cy is cyclohexyl), two phosphido‐bridged dirhenium groups are linked by a Pt(CO)2 unit and show different bonding patterns for stereochemical reasons. The Re—Re distances are 3.2620 (15) and 3.0739 (15) Å, and the Pt—Re distances are 2.9165 (12), 2.9025 (15) and 2.8548 (13) Å. |
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