Potassium bis(carbonato‐O,O′)(ethylenediamine‐N,N′)cobaltate(III) monohydrate at 173 K |
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Authors: | Nebebech Belai Michael H Dickman Michael T Pope |
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Abstract: | The title salt, KCo(C2H8N2)(CO3)2]·H2O, consists of a distorted octahedral cobalt complex anion and a seven‐coordinate potassium cation. Both metal atoms have crystallographic twofold symmetry, one C2 axis passing through the Co atom and C—C bond, and another along a short K—O (water) bond of 2.600 Å (corrected for libration). The carbonate is bidentate to both cobalt and potassium and the water forms a hydrogen bond to a carbonate O atom. |
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