(3R,4aS,5R)‐3‐Hydroxy‐5‐isopropenyl‐3,8‐dimethyl‐4,4a,5,6‐tetrahydro‐2(3H)‐naphthalenone |
| |
Authors: | Dianne D Ellis Anthony L Spek |
| |
Abstract: | In the crystal structure of C15H20O2, molecules are associated by intermolecular hydrogen bonds between the hydroxy function and a keto group O?O 2.770 (2) Å], forming chains along the 100] direction in the crystal. Both six‐membered rings in the decalin unit adopt envelope conformations; one section of the molecule, encompassing the extended conjugation of a C=C double bond with an enone functionality C=C—C=O = 175.6 (2)° and C=C—C=C = 176.6 (2)°], is flat, whilst the rest of the molecule is folded relative to the constrained part. The stereochemistry was determined from the R‐(–)‐carvone starting material. |
| |
Keywords: | |
|
|