Tetracarbonyl(diphenyldithiophosphinato‐S,S′)rhenium(I) |
| |
| Authors: | Soledad Garcí a Font n,Elvira Lamas Castro,Pilar Rodrí guez Seoane,Ezequiel M. V zquez‐L pez |
| |
| Affiliation: | Soledad García Fontán,Elvira Lamas Castro,Pilar Rodríguez Seoane,Ezequiel M. Vázquez‐López |
| |
| Abstract: | The title compound consists of [Re(C12H10PS2)(CO)4] molecules in which the Re atom is octahedrally coordinated by four carbonyl groups and two dithiophosphinate S atoms. The main coordination distortion is imposed by the ligand bite angle of 78.29 (4)°. The bidentate coordination of the dithiophosphinate ligand involves almost equal Re—S [2.5366 (15) and 2.5535 (14) Å] and P—S distances [2.0100 (19) and 2.0212 (19) Å]. |
| |
| Keywords: | |
|
|
