Tetrakis(2‐amino‐5‐methyl‐1,3,4‐thiadiazole‐N3)chlorocopper(II) chloride monohydrate and tetrakis(2‐amino‐5‐ethyl‐1,3,4‐thiadiazole‐N3)chlorocopper(II) chloride |
| |
Authors: | Daniel E Lynch Jonathan Ewington |
| |
Abstract: | The structures of the title compounds, CuCl(C3H5N3S)4]Cl·H2O, (I), and CuCl(C4H7N3S)4]Cl, (II), comprise square‐pyramidal Cu centres with four N‐bound organic ligands filling the base positions, a Cl atom in the apical position and a Cl? as a free counter‐ion. The cation and free chloride ion in (II) have fourfold crystallographic symmetry. Hydrogen‐bonding associations from the 2‐amino H atoms dominate both structures, with the principal acceptors being the chlorides, although in (I), the N4 atoms are also involved. Furthermore, (I) is a hydrate, with the water molecule participating in the hydrogen‐bonding network. |
| |
Keywords: | |
|
|