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Green synthesis and characterization of Ag and Ag/Fe3O4 nanocomposites for antimicrobial effect and rhodamine- B dye degradation
Authors:K Saravanan  M. Ilayaraja  P. Muthukrishnan  S. Ananthakrishnan  P. Ravichandiran
Affiliation:1. Department of Chemistry, Roever Engineering College, Perambalur, 621212, Tamilnadu, India;2. Department of Chemistry, Arumugam Pillai Seethai Ammal College, Tiruppattur, 630 211, Tamilnadu, India;3. Department of Chemistry, Faculty of Engineering, Karpagam University (Karpagam Academy of Higher Education), Coimbatore, 641 021, Tamilnadu, India
Abstract:We used a simple two-stage tactic to design and synthesize a magnetically separable catalyst (MSC) Ag/Fe3O4 by combining independently synthesized Fe3O4 and Jatropha curcas root functionalized Ag nanoparticles (NPs) at room temperature. The phase composition of Ag/Fe3O4 NCs was revealed by morphological and structural assessment. The derived Ag/Fe3O4 nanocomposites demonstrated outstanding antimicrobial activity against Gram-negative Pseudomonas aeruginosa comparing to Gram-positive Bacillus subtilis which was determined by the agar well diffusion method. This is due to positively charged surface of metal oxide NPs that may bind to cell membrane. Interestingly, Ag–Fe3O4 NCs demonstrated good photocatalytic activity for organic dye degradation. According to a kinetic study, Ag/Fe3O4 MSC removed 99% of Rhodamine B at a rate constant of 1.89 min?1. The photoelectron could perhaps ultimately collide only with dissolved solids in the substrate to form superoxides, which can damage the dye. Notably, the MSCs reusability was tested using magnetic detachment without sacrificing photocatalytic efficiency. This finding represents a significant breakthrough in the domain of wastewater treatment and biomedicine.
Keywords:JC-Root  Green approach  Rhodamine B dye  Reusability
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