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The development of platinum-rhodium alloy coatings on SS304 using a pulse/direct electrodeposition technique and their application to antibacterial activity
Authors:Bharath K. Devendra  B.M. Praveen  V.S. Tripathi  H.P. Prashanth Kumar  K.R. Chethana
Affiliation:1. Department of Chemistry, Srinivas University, Institute of Engineering & Technology, Mukka, Karnataka, Mangaluru, 574146, India;2. Department of Chemistry, M.S. Ramaiah College of Arts, Science and Commerce, MSR Nagar, MSRIT Post, Bengaluru, 560054, India;3. Radiation & Photochemistry Division, Bhabha Atomic Research Centre, Maharashtra, Mumbai, Trombay, 400085, India;4. Department of Biotechnology, Sapthagiri College of Engineering, Hesaraghatta, Karnataka, Bengaluru, 560057, India
Abstract:The current research focused on the development of Platinum–Rhodium alloy coating (Pt– Rh) on SS304 and its applications in antibacterial studies. Electrodeposition is considered to be one of the most suitable methods because it enhances the therapeutic effects of noble metals (Pt–Rh alloy). The electrodeposited coating is an economical and time-saving alternative to existing coating methods. The newly developed Pt–Rh coating was investigated using a scanning electron microscope (SEM) and an atomic force microscope (AFM). Using the agar Petri plate and broth culture method, the antibacterial effect of the platinum-rhodium alloy was investigated against Gram-negative Escherichia coli and Gram-positive bacteria such as Staphylococcus saprophytes, Bacillus Subtilis, and Enterococcus faecalis. The Pt–Rh alloy coated samples obtained by Direct current (DC) and Pulse coating (PC 50% and PC 75%) were examined for antibacterial study. The PC 75% Pt–Rh alloy coating exhibits significant antibacterial activity, demonstrating a maximum zone of inhibition while leaving the rest of the coated samples by DC and PC 50% duty cycles. The study also found that when the concentration of Pt–Rh solution rises from 5 μL to 15 μL, so does the antibacterial activity. The findings of the study showed that electrodeposited platinum-rhodium alloy metal ions may be handy bacteriostatic in the coming years.
Keywords:Electrodeposition  Platinum–rhodium alloy  SEM  AFM  Antibacterial activity
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