| 四氢呋喃阳离子聚合向丁二酸酐链转移反应的研究 |
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| 引用本文： | 魏斌,赵庆香,栗方星. 四氢呋喃阳离子聚合向丁二酸酐链转移反应的研究[J]. 化学研究与应用, 1996, 0(2) |
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| 作者姓名： | 魏斌 赵庆香 栗方星 |
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| 作者单位： | 南开大学化学系 |
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| 摘 要： | 四氢呋喃阳离子聚合向丁二酸酐链转移反应的研究魏斌，赵庆香，栗方星（南开大学化学系天津３０００７１）关键词聚四氢呋喃，五氯化锑，表现链转移速率常数，表现聚合反应速率常数前言在用ＣＨ３ＣＯＳｂＣｌ５引发的四氢呋喃阳离子聚合［１］过程中，我们发现存在着活性...
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| 关 键 词： | 聚四氢呋喃，五氯化锑，表现链转移速率常数，表现聚合反应速率常数 |
STUDING OF THE CHAIN TRANSFER REACTION OF THE TETRAHYDROFURAN CATIONIC POLYMERIZATION TO SUCCINIC ANHYDRIDE |
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| Wei Bin,Zhao Qingxiang,Li Fanxing. STUDING OF THE CHAIN TRANSFER REACTION OF THE TETRAHYDROFURAN CATIONIC POLYMERIZATION TO SUCCINIC ANHYDRIDE[J]. Chemical Research and Application, 1996, 0(2) |
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| Authors: | Wei Bin Zhao Qingxiang Li Fanxing |
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| Abstract: | In the tetrahydrofuran cationic polymerization initiated by CH-3OCSbCl_5,the chain transfer reaction from active center to succinic anhydride is found. The apparent chain transfer rate constant ktr for the chain transfer reaction and the apporent pohymerization rate constant kp are determined. In the Paper,we also investigate the influence of the chain transfer on the polytetrahydrofuran tensile strength and the potential value for the exploitation. |
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| Keywords: | Polytetrahydrofuran SbCl_5 Apparent chain transfer rate constant Apparent polymerization rate constant |
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