Hydrolysis of 2-alkoxyalk-2-enals |
| |
Authors: | T. N. Mamashvili N. A. Keiko G. I. Sarapulova M. G. Voronkov |
| |
Affiliation: | (1) Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation |
| |
Abstract: | Hydrolysis of 2-alkoxyalk-2-enals with equimolar amount of water (in an organic solvent) and with an excess of water has been studied with the aim of synthesizing 2-oxopropanal (methylglyoxal). 2-Oxopropanal obtained in an excess of water exists in the hydrate from. In organic solvents, the cyclic trimer of 2-oxopropanal, 2,4,6-triacetyl-1,3,5-trioxane, predominates (NMR data). Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2547–2549, December, 1998. |
| |
Keywords: | 2-alkoxyalk-2-enals hydrolysis 2-oxopropanal (methylglyoxal) 2,4,6-triacetyl-1,3,5-trioxane |
本文献已被 SpringerLink 等数据库收录! |
|