Hydrolysis of 2-alkoxyalk-2-enals |
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| Authors: | T N Mamashvili N A Keiko G I Sarapulova M G Voronkov |
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| Institution: | (1) Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation |
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| Abstract: | Hydrolysis of 2-alkoxyalk-2-enals with equimolar amount of water (in an organic solvent) and with an excess of water has been
studied with the aim of synthesizing 2-oxopropanal (methylglyoxal). 2-Oxopropanal obtained in an excess of water exists in
the hydrate from. In organic solvents, the cyclic trimer of 2-oxopropanal, 2,4,6-triacetyl-1,3,5-trioxane, predominates (NMR
data).
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2547–2549, December, 1998. |
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| Keywords: | 2-alkoxyalk-2-enals hydrolysis 2-oxopropanal (methylglyoxal) 2 4 6-triacetyl-1 3 5-trioxane |
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