Induction of trimeric [Mg3(OH)(CO2)6] in a porous framework by a desymmetrized tritopic ligand |
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| Authors: | Zhai Quanguo Lin Qipu Wu Tao Zheng Shou-Tian Bu Xianhui Feng Pingyun |
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| Affiliation: | Department of Chemistry, University of California, Riverside, CA 92521, USA. |
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| Abstract: | The use of a desymmetrized tritopic ligand with both carboxyl and pyridyl functionalities leads to the first occurrence of the [Mg(3)(μ(3)-OH)(CO(2))(6)] trimer as the 3-D framework building block in a porous crystal that shows relatively high H(2) uptake (1.37% at 77 K and 1 atm). |
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