| 配合物Cu(C14H10N2O2)(C5H5N)的合成和晶体结构 |
| |
| 引用本文： | 卢文贯,冯小龙,刘宏文,王少玲. 配合物Cu(C14H10N2O2)(C5H5N)的合成和晶体结构[J]. 无机化学学报, 2003, 19(2): 206-210 |
| |
| 作者姓名： | 卢文贯 冯小龙 刘宏文 王少玲 |
| |
| 作者单位： | 1. 韶关学院化学系,韶关,512005
2. 中山大学分析测试中心,广州,510275 |
| |
| 摘 要： | The novel copper(Ⅱ) complex with salicylaldehyde benzoylhydrazone and pyridine ligands， Cu(C14H10N2O2)(C5H5N)， has been synthesized and characterized by elemental analysis， IR and thermal analysis. The crystal structure of the title complex has been determined by single crystal X-ray diffraction techniques. The crystal belongs to monoclinic with space group P21/c. The cell parameters are： a=1.6362(9)nm， b=1.7140(9)nm， c=1.2255(7)nm， β=105.168(9)°， V=3.317(3)nm3， Z=8， Dc=1.525g·cm-3， μ(MoKα)=1.334mm-1， F(000)=1560. The structure was refined to final R1=0.0376， wR2=0.0909. The copper(Ⅱ) ion lies in a dis-torted square-planar environment composed of two oxygen atoms， one nitrogen atom of tridentate acyhydrazone Schiff base ligand and one nitrogen atom of the pyridine ligand. CCDC： 193111.
|
| 关 键 词： | Schiff碱 酰腙 铜(Ⅱ)配合物 晶体结构 |
| 修稿时间： | 2002-08-22 |
Synthesis and Crystal Structure of Complex Cu(C14H10N2O2)(C5H5N) |
| |
| LU Wen-Guan,FENG Xiao-Long,LIU Hong-Wen and WANG Shao-Ling. Synthesis and Crystal Structure of Complex Cu(C14H10N2O2)(C5H5N)[J]. Chinese Journal of Inorganic Chemistry, 2003, 19(2): 206-210 |
| |
| Authors: | LU Wen-Guan FENG Xiao-Long LIU Hong-Wen WANG Shao-Ling |
| |
| Abstract: | |
| |
| Keywords: | schiff base acyhydrazone copper?complex crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
|
点击此处可从《无机化学学报》下载全文 |
