Low-power high-resolution solid-state NMR of peptides and proteins |
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Authors: | Ernst Matthias Meier Marcel A Tuherm Tiit Samoson Ago Meier Beat H |
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Institution: | Physical Chemistry, ETH-Zürich, CH-8093 Zürich, Switzerland. |
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Abstract: | We demonstrate that two-dimensional solid-state NMR chemical-shift correlation spectra can be recorded under low-power conditions. Except for the cross-polarization period, no rf-field amplitudes above 40 kHz are used. Such experiments require the use of fast (>50 kHz) magic-angle spinning (MAS). A comparison with the high-power version of the experiment shows no general line broadening but some changes in the polarization-transfer dynamics. |
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