Relaxation effect on the Onsager coefficients of mixed strong electrolytes in the mean spherical approximation |
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| Authors: | Van Damme Steven Deconinck Johan |
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| Affiliation: | Computational Electrochemistry Group, Department of Electrotechnics and Power Electronics, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussel, Belgium. stvdamme@vub.ac.be |
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| Abstract: | The Fuoss-Onsager continuity equations are solved by using the equilibrium pair distribution functions of the mean spherical approximation in the case of equal diameters. An analytical expression is obtained for the relaxation effect on the Onsager coefficients of mixed strong electrolytes. This work also extends the existing expressions for the conductivity of binary and ternary electrolytes to any number of ions. |
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