Total synthesis of a marine alkaloid from the tunicate Dendrodoa grossularia |
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Authors: | Hupp Christopher D Tepe Jetze J |
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Affiliation: | Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA. |
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Abstract: | A short synthesis of an indole marine alkaloid (1) from the tunicate Dendrodoa grossularia is described. The key step in the synthesis involves a novel twist on an underutilized oxazole rearrangement, which produces the quaternary stereocenter in the molecule. |
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