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Concise synthesis of bicyclic aminals and their evaluation as precursors to the sarain core
Authors:Price Mortimer Anne J  Pang Pui Shan  Aliev Abil E  Tocher Derek A  Porter Michael J
Affiliation:Department of Chemistry, University College London, Christopher Ingold Building, 20 Gordon Street, London, UKWC1H 0AJ.
Abstract:A number of bicyclic aminals have been prepared in a stereospecific manner as potential precursors to the core structure of the sarain alkaloids. Rearrangement of these aminals to new diazabicyclic and diazatricyclic systems has been observed under various conditions.
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