Concise synthesis of bicyclic aminals and their evaluation as precursors to the sarain core |
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Authors: | Price Mortimer Anne J Pang Pui Shan Aliev Abil E Tocher Derek A Porter Michael J |
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Affiliation: | Department of Chemistry, University College London, Christopher Ingold Building, 20 Gordon Street, London, UKWC1H 0AJ. |
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Abstract: | A number of bicyclic aminals have been prepared in a stereospecific manner as potential precursors to the core structure of the sarain alkaloids. Rearrangement of these aminals to new diazabicyclic and diazatricyclic systems has been observed under various conditions. |
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