Stereospecific mannosylations of myo -inasitol: Synthesis of manno- myo -inositol fragment of Mycobacterium tuberculosis |
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| Authors: | Hari Babu Mereyala and Bapu Reddy Gaddam |
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| Institution: | (1) Bio-Organic Laboratory, Indian Institute of Chemical Technology, 500007 Hyderabad, India |
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| Abstract: | Methyl iodide activated stereospecific α-mannosylations utilising 2-pyridyl-1-thiomannopyranoside derivatives (2,3,4) as donors
and suitably protected myo-inositol derivatives (1,25,27,29) as acceptors to prepare 2-0-α-D-mannopyranosyl-6-O-α-D-mannopyranosyl-(1–6)-O-α-D-mannopyranosyl-(l-6)-O-α-D-mannopyranosyl]-D-myo-inositol derivative (31) is described.
IICT Commun. No. 3355 |
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| Keywords: | Stereospecific mannosylations myo-inositol Mycobacterium tuberculosis |
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