| Schiff碱铜(Ⅰ)配合物的合成、结构及其与DNA相互作用的研究 |
| |
| 引用本文： | 蔡铁军,彭振山,邓 谦,龙云飞,邓彤彤,郁开北.Schiff碱铜(Ⅰ)配合物的合成、结构及其与DNA相互作用的研究[J].无机化学学报,2004,20(6):731-733. |
| |
| 作者姓名： | 蔡铁军 彭振山 邓 谦 龙云飞 邓彤彤 郁开北 |
| |
| 作者单位： | 1. 湖南科技大学化学化工学院,湘潭,411201
2. 中科院成都有机化学研究所,成都,610041 |
| |
| 摘 要： | A Cu(Ⅰ) complex Cu(INHPy)(PPh3)2] ·(ClO4)·0.75(C2H5OH) was obtained through self-assembly between Cu(PPh3)2(MeCN)2]ClO4 and Schiff base 2-pyridylcarboxaldehyde isonicotinoyl hadrazone(INHPy), the structure of which was characterized by elemental analysis, IR spectrum and X-ray diffraction. Single crystal X-ray analysis indicates that this compound crystallizes in triclinic system, space group P1 with parameters: a=1.180 7(2) nm, b=1.330 0(3) nm, c=1.568 6(2) nm. α=100.91(1)°, β=108.863(2)°, γ=95.51(2)°. V=2.382 0(7) nm3, Z=4 , Dc=1.332 g·cm-3, F(000)=1 032, μ=0.634 mm-1. At the same time, we studied the title complex interacting with DNA with resonance light-scattering spectrum. The results showed that intensities of RLS signal are direct proportion to the concentration of DNA, (ΔI=0.804+23.770C, r=0.995). CCDC: 231388.
|
| 关 键 词： | 自组装 铜(Ⅰ)化合物 晶体结构 DNA 共振光散射光谱 |
| 修稿时间： | 2003年12月2日 |
Studies on the Synthesis, Structure of the Schiff Base Copper(Ⅰ) Complex and Its Interaction with DNA |
| |
| CAI Tie-Jun,PENG Zhen-Shan,DENG Qian,LONG Yun-Fei,DENG Tong-Tong and YU Kai-Bei.Studies on the Synthesis, Structure of the Schiff Base Copper(Ⅰ) Complex and Its Interaction with DNA[J].Chinese Journal of Inorganic Chemistry,2004,20(6):731-733. |
| |
| Authors: | CAI Tie-Jun PENG Zhen-Shan DENG Qian LONG Yun-Fei DENG Tong-Tong and YU Kai-Bei |
| |
| Institution: | College of Chemistry and Chemical Engineeing, Hunan University of Science and Technology, Xiangtan 411201,College of Chemistry and Chemical Engineeing, Hunan University of Science and Technology, Xiangtan 411201,College of Chemistry and Chemical Engineeing, Hunan University of Science and Technology, Xiangtan 411201,College of Chemistry and Chemical Engineeing, Hunan University of Science and Technology, Xiangtan 411201,College of Chemistry and Chemical Engineeing, Hunan University of Science and Technology, Xiangtan 411201 and Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 |
| |
| Abstract: | |
| |
| Keywords: | |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
