| Synthesis and Crystal Structure of Bis（2-acetylpyridine thiosemicarbazonato）-indium（iii） Perchlorate Hydrate |
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| 引用本文： | WANG Le,BIAN Wei-Wei,ZHU Ling,NI Rong-Jun,TAO Lin. Synthesis and Crystal Structure of Bis（2-acetylpyridine thiosemicarbazonato）-indium（iii） Perchlorate Hydrate[J]. 结构化学, 2011, 30(6): 882-886 |
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| 作者姓名： | WANG Le BIAN Wei-Wei ZHU Ling NI Rong-Jun TAO Lin |
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| 作者单位： | [1]（State Key Laboratory of Ceramic, Zibo Entry andExit Inspection and Quarantine Bureau, Zibo 255031, China [2]Department of Medical Chemistry, Weifang Medical University, Weifang 261053, China |
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| 基金项目： | Financially supported from the Science Research Foundation of Shandong Entry-Exit Inspection; Quarantine Bureau （No. SK201042）; Weifang Medical University （No. KQ2007030） |
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| 摘 要： | The title complex bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) perchlo-rate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide(L) with indium(iii) perchlorate,and its structure was characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal of the title compound([In(C8H9N4S)2]ClO4·H2O) belongs to monoclinic,space group P21/c with a = 12.6438(18),b = 12.6259(18),c = 15.116(2) nm,β = 105.800(2)°,Z = 4,V = 2321.9(6) nm3,Mr = 618.79,Dc = 1.770 g/cm3,μ = 1.359 mm-1,F(000) = 1240,R = 0.0265 and wR = 0.0675.X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules.
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| 关 键 词： | 晶体结构 高氯酸盐 水合物 III 合成 乙酰 X射线衍射分析 标题化合物 |
Synthesis and Crystal Structure of Bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) Perchlorate Hydrate |
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| WANG Le,BIAN Wei-Wei,ZHU Ling,NI Rong-Jun,TAO Lin. Synthesis and Crystal Structure of Bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) Perchlorate Hydrate[J]. Chinese Journal of Structural Chemistry, 2011, 30(6): 882-886 |
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| Authors: | WANG Le BIAN Wei-Wei ZHU Ling NI Rong-Jun TAO Lin |
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| Affiliation: | 1. State Key Laboratory of Ceramic, Zibo Entry and Exit Inspection and Quarantine Bureau, Zibo 255031, China
2. Department of Medical Chemistry, Weifang Medical University, Weifang 261053, China |
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| Abstract: | The title complex bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) perchlorate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide (L) with indium(iii) perchlorate, and its structure was characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal of the title compound ([In(CsH9N4S)2]ClO4·H2O)belongs to monoclinic, space group P21/c with a = 12.6438(18), b = 12.6259(18), c = 15.116(2) nm,β = 105.800(2)°, Z = 4, V= 2321.9(6) nm3, Mr = 618.79, Dc = 1.770 g/cm3, μ = 1.359 mm-1, F(000)= 1240, R = 0.0265 and wR = 0.0675. X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules. |
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| Keywords: | self-assembly cationic complex polyatomic counterion hydrogen-bond |
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