Ru(III) catalyzed oxidation of some aliphatic alcohols by N-bromosuccinimide (NBS). A kinetic study |
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| Authors: | P Giridhar Reddy A Venkat Reddy A Ratnamala S Venkateswara Rao and Sushama Kandlikar |
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| Institution: | (1) Department of Chemistry, Nizam College, (O. U.), Hyderabad-500 001, India |
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| Abstract: | Kinetics of Ru(III) catalyzed oxidation of methanol, ethanol, n-propanol, n-butanol, isopropanol and iso-butanol by N-bromosuccinimide (NBS) in the presence of Hg(II) acetate have been studied in acid medium. The oxidation exhibits a fractional order in alcohol] and first order in NBS]. The applicability of Taft's equation was tested. The probable mechanism is discussed.
            ,  , -  , -  ,   -  (   )  Hg(II), Ru(III),   .   .   .  .
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