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Diffusion in inhomogeneous films and membranes
Authors:HL Frisch
Institution:Department of Chemistry, State University of New York at Albany, Albany, New York 12222 U.S.A.
Abstract:In a number of different contexts one is interested in the diffusion of a penetrant into an inhomogeneous film or membrane. We review exact results in the theory of permeation through membranes containing fixed inhomogeneities. We also present the available exact results on permeation, time lag, and sorption for a sufficiently dilute penetrant in an inhomogeneous slab or film. We discuss and compare the kind of information provided by permeation and sorption studies using a variety of examples of simple types of inhomogeneities.
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