Electrochemical studies of copper fatty amides complex in organic medium |
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Authors: | Ali Abdulabbas Abdullah Emad A Jaffar Al-Mulla Isam Hussain T Al-Karkhi Saadon Abdulla Aowda |
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Institution: | 1. Department of Electrical Engineering, Al-Mussaib Technical College, Foundation of Technical Education, Babylon, Iraq 2. Department of Chemistry, College of Science, University of Kufa, P.O. Box 21, An-Najaf, 54001, Iraq 3. Department of Basic Science, College of Dentistry, University of Baghdad, Al-Jadrya-Baghdad, Iraq 4. Department of Chemistry, College of Science, University of Babylon, Babylon, Iraq
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Abstract: | The electrochemical behavior of complexes of fatty amides, synthesized from vegetable oil, with Cu(II) has been investigated. In this study, a platinum electrode was used in presence of DMSO as a medium. Reduction of Cu(II)/fatty amides complex was found with quasi-reversible reaction. The peak potential of voltammetric behavior of fatty amides is about ?0.77 V at a scan rate v = 0.1 V s?1 versus Ag|Ag+ electrode. This study shows that Cu(II)-fatty amides complex is poorly adsorbed on the electrode surface. Additionally, the copper complex form of fatty amides has a more stable structure than pure fatty amides to form the electrochemical reduction of the complex. |
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