| 锐钛矿相TiO2纳米管的制备及其染料敏化太阳电池 |
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| 引用本文： | 张 苑,赵 颖,蔡 宁,熊绍珍. 锐钛矿相TiO2纳米管的制备及其染料敏化太阳电池[J]. 物理学报, 2008, 57(9): 5806-5809 |
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| 作者姓名： | 张 苑 赵 颖 蔡 宁 熊绍珍 |
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| 作者单位： | 南开大学光电子薄膜器件与技术研究所，天津 300071 |
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| 基金项目： | 天津市重点基金(批准号：06YFJZJC01700)和国家重点基础研究发展规划973项目(批准号：2006CB202602、2006CB202603)资助的课题. |
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| 摘 要： | 以商用金红石相TiO2粉末为原料，通过在碱性溶液中150℃水热48h的方法合成TiO2纳米管.采用SEM，TEM，XRD分析手段对TiO2纳米管的形貌和结构演变进行了表征.制成的TiO2纳米管与TritonX-100，乙酰丙酮混合后，通过丝网印刷的方法涂敷到ITO导电玻璃衬底上，并且在450℃下烧结30min后得到可应用于染料敏化太阳电池的多孔光阳极.将此光阳极浸泡于N719染料敏化后，与镀铂对电极组装电池，两者之间灌关键词：2纳米管')" href="#">TiO2纳米管染料敏化太阳电池水热法
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| 关 键 词： | TiO2纳米管 染料敏化太阳电池 水热法 |
| 收稿时间： | 2007-09-30 |
Preparation of anatase TiO2 nanotubes and their dye-sensitized solar cells |
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| Zhang Yuan,Zhao Ying,Cai Ning and Xiong Shao-Zhen. Preparation of anatase TiO2 nanotubes and their dye-sensitized solar cells[J]. Acta Physica Sinica, 2008, 57(9): 5806-5809 |
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| Authors: | Zhang Yuan Zhao Ying Cai Ning Xiong Shao-Zhen |
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| Abstract: | TiO2 nanotubes were synthesized from commercial rutile powder by means of the hydrothermal method in alkaline solution at temperature of 150℃ for 48hours. The morphology and structure evolutions were characterized with SEM，TEM and X-ray diffraction. The TiO2 nanotubes mixed with Triton X-100 and acetyl acetone were screen-printed onto the glass substrate coated with a transparent conducting oxide (ITO，or tin-doped indium oxide)，then sintered at 450℃ for 30 minutes to form porous photoanode of dye-sensitized solar cells. A solar cell withactive area of 0.28cm2 was assembled with N719-coated nanotube-TiO2 electrode，Pt-coated ITO glass and iodide-based ionic liquid electrolyte. The J-V curve was measured using a standard solar simulator (AM1.5 spectrum，100mW/cm2)，and a photoelectric conversion efficiency of 2.17% was obtained. |
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| Keywords: | TiO2 nanotube dye sensitized solar cells hydrothermal method |
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