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Synthesis and Properties of the Alkyl/Aryl Germanium Dioximates Containing Ge─O Bond: Stability Factors—A Theoretical Approach |
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| Authors: | Raji Thomas Nelson Joseph P Pushpa Pardasani T Mukherjee |
| Abstract: | The reactions of R2GeCl2 and R3GeCl with 9,10‐phenanthrenequinone dioxime in 1:1 and 1:2 molar ratios to form a series of organogermanium complexes of the general formula R2GeL and (R3Ge)2L R=Me, Et, Ph] have been investigated. The physical and spectral properties of all derivatives are described. In addition, the nature of Ge─O bond has been studied by using the DFT/B3LYP method. |
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