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Specific Features of Strain Dependences of Loss Modulus in Highly Stretched Elastomers
Authors:Igor P Borodin  Tatyana I Borodina  Theodor N Khazanovich
Abstract:The loss modulus E″ in elastomer strips stretched by a factor of λ is studied theoretically. A small oscillating deformation is applied to these strips in the transition frequency zone between the glassy and rubbery states. The range of λ under study ranges up to ultimate extensions close to fracture. A model of E″/λ dependence in the transition frequency zone is suggested that considers the possible distortion in the local chain structure in the ultimate extension range. It is found that E″ in the range of moderate and high λ increases owing to the finite extensibility of the chains. However, upon further extension up to ultimate values, E″ decreases and a maximum appears on the E″/λ curves. These features are also confirmed experimentally.
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Keywords:large strains  loss modulus  networks  polymer chains  structure distortions
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