Abstract: | A strategy to fabricate nanostructured poly(3‐hexylthiophene) (P3HT) films for organic photovoltaic (OPV) cells by a direct transfer method from a reusable soft replica mold is presented. The flexible polyfluoropolyether (PFPE) replica mold allows low‐pressure and low‐ temperature process condition for the successful transfer of nanostructured P3HT films onto PEDOT/PSS‐coated ITO substrates. To reduce the fabrication cost of masters in large area, we employed well‐ordered anodic aluminum oxide (AAO) as a template. Also, we provide a method to fabricate reversed nanostructures by exploiting the self‐replication of replica molds. The concept of the transfer method in low temperature with a flexible and reusable replica mold obtained from an AAO template will be a firm foundation for a low‐cost fabrication process of ordered OPVs. |