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A new type of lithium-ion cell based on the Li4Ti5O12/Li2Co0.4Fe0.4Mn3.2O8 high-voltage,electrode combination
Institution:1. Czestochowa University of Technology, Department of Chemistry, Al. Armii Krajowej 19, 42-200, Czestochowa, Poland;2. Poznan University of Technology, Institute of Materials Science and Engineering, Jana Pawla II no 24, 61-138, Poznan, Poland;1. Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China;2. Department of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081, China;1. Guangxi Key Laboratory of Information Materials, School of Materials Science and Engineering, and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials, Guilin University of Electronic Technology, Guilin 541004, PR China;2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, PR China;3. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, PR China;1. Electrochemical Energy Conversion and Storage Systems Group, Institute for Power Electronics and Electrical Drives (ISEA), RWTH Aachen University, Jägerstrasse 17/19, 52066, Aachen, Germany;2. Institute for Power Generation and Storage Systems (PGS), E.ON ERC, RWTH Aachen University, Mathieustrasse 10, 52074 Aachen, Germany;3. Jülich Aachen Research Alliance, JARA-Energy, Templergraben 55, 52056 Aachen, Germany;4. Helmholtz Institute Münster (HI MS), IEK-12, Forschungszentrum Jülich, Jägerstrasse 17-19, 52066 Aachen, Germany
Abstract:A new type of lithium-ion cell based on the combination of a high voltage spinel LiLi1/3 Ti5/3]O4 anode with a high voltage mixed spinel solid solution Li2(M1M2)xMn3?xO8 cathode, is described. Although somewhat affected by the instability of the electrolyte in the charge region, the cell operates along the expected voltage levels, this demonstrating the feasibility of this innovative concept in the advanced lithium ion battery technology.
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