Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination |
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| Authors: | Higginbotham Mari C M Bebbington Magnus W P |
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| Affiliation: | Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh EH14 4AS, UK. |
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| Abstract: | Six-membered cyclic sulfamidates are prepared in high yields by treatment of allenic sulfamates with readily available gold(I) complexes. The reaction enables formation of N-substituted quaternary centres and complements existing processes for sulfamidate formation. |
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