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Borylene transfer from an iron bis(borylene) complex: synthesis of 1,4-diboracyclohexadiene and 1,4-dibora-1,3-butadiene complexes
Authors:Braunschweig Holger  Ye Qing  Radacki Krzysztof  Damme Alexander
Affiliation:Institut für Anorganische Chemie, Bayerische Julius‐Maximilians‐Universit?t Würzburg, Am Hubland, 97074 Würzburg (Germany) http://www‐anorganik.chemie.uni‐wuerzburg.de/Braunschweig/index.html
Abstract:Diene to be made: By tuning the size of acetylenic substituents, 1,4-diboracyclohexadiene and unprecedented 1,4-dibora-1,3-butadiene complexes were generated in a controlled manner by borylene transfer from an iron bis(borylene) complex to alkynes (see scheme).
Keywords:boraheterocycles  boron  borylene complexes  iron  photochemistry
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