Borylene transfer from an iron bis(borylene) complex: synthesis of 1,4-diboracyclohexadiene and 1,4-dibora-1,3-butadiene complexes |
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| Authors: | Braunschweig Holger Ye Qing Radacki Krzysztof Damme Alexander |
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| Institution: | Institut für Anorganische Chemie, Bayerische Julius‐Maximilians‐Universit?t Würzburg, Am Hubland, 97074 Würzburg (Germany) http://www‐anorganik.chemie.uni‐wuerzburg.de/Braunschweig/index.html |
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| Abstract: | Diene to be made: By tuning the size of acetylenic substituents, 1,4-diboracyclohexadiene and unprecedented 1,4-dibora-1,3-butadiene complexes were generated in a controlled manner by borylene transfer from an iron bis(borylene) complex to alkynes (see scheme). |
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| Keywords: | boraheterocycles boron borylene complexes iron photochemistry |
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