| Radical Addition and Substitution Reactions of (η6-Arene)-tricarbonylmetal Complexes |
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| 引用本文： | LIN He-Chun YANG Li LI Chao-Zhong. Radical Addition and Substitution Reactions of (η6-Arene)-tricarbonylmetal Complexes[J]. 有机化学, 2003, 23(Z1): 207-208 |
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| 作者姓名： | LIN He-Chun YANG Li LI Chao-Zhong |
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| 作者单位： | LIN He-Chun（State Key Laboratory of Applied Chemistry, Lanzhou University, Lanzhou 730000） YANG Li（State Key Laboratory of Applied Chemistry, Lanzhou University, Lanzhou 730000） LI Chao-Zhong（Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032） |
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| 摘 要： | We report here the first alkyl radical additions of (η6-arene)tricarbonylmanganese complexes in the presence of alkylmercury chloride and NaI (Eq. 1). The mechanism was postulated to be the alkyl radical addition to ArMn- (CO)+3 cation to form the corresponding 17 valence electron intermediate, which was then reduced by alkylmercury chloride via a single electron transfer process to afford the product and regenerate an alkyl radical. [1]
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Radical Addition and Substitution Reactions of (η6-Arene)-tricarbonylmetal Complexes |
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| LIN He-Chun,YANG Li. Radical Addition and Substitution Reactions of (η6-Arene)-tricarbonylmetal Complexes[J]. Chinese Journal of Organic Chemistry, 2003, 23(Z1): 207-208 |
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| Authors: | LIN He-Chun YANG Li |
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| Abstract: | We report here the first alkyl radical additions of (η6-arene)tricarbonylmanganese complexes in the presence of alkylmercury chloride and NaI (Eq. 1). The mechanism was postulated to be the alkyl radical addition to ArMn- (CO)+3 cation to form the corresponding 17 valence electron intermediate, which was then reduced by alkylmercury chloride via a single electron transfer process to afford the product and regenerate an alkyl radical. [1] |
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