A "cation-less" oxalate-based ferromagnet formed by neutral bimetallic layers: {[Co(H2O)2]3[Cr(ox)3]2(18-crown-6)2}(infinity) (ox = oxalate dianion; 18-crown-6 = C12H24O6) |
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| Authors: | Coronado Eugenio Galan-Mascarós José R Martí-Gastaldo Carlos |
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| Institution: | Instituto de Ciencia Molecular, Universidad de Valencia y Fundación General de la Universidad de Valencia, Polígono de la Coma s/n, 46980 Paterna, Spain. eugenio.coronado@uv.es |
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| Abstract: | Neutral layers of the bimetallic oxalate complex {Co(H2O)2]3Cr(ox)3]2}infinity are formed in the presence of a crown ether and stabilized by hydrogen bonding. The resulting soluble ferromagnet orders at Tc = 7.4 K. |
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