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Dark uncertainty
Authors:Michael Thompson  Stephen L. R. Ellison
Affiliation:(1) School of Science, Birkbeck University of London, Malet Street, London, WC1E 7HX, UK;(2) LGC Ltd, Queens Road, Teddington, Middlesex, TW11 0LY, UK
Abstract:Standard uncertainties obtained by the GUM approach for a range of analytical methods are compared directly and indirectly with estimates of reproducibility standard deviation for the same methods. Results were obtained from both routine analysis and international key comparisons. A general tendency for the uncertainty to be substantially less than the reproducibility standard deviation was found.
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